全文获取类型
收费全文 | 182篇 |
免费 | 13篇 |
国内免费 | 56篇 |
专业分类
安全科学 | 9篇 |
废物处理 | 5篇 |
环保管理 | 25篇 |
综合类 | 89篇 |
基础理论 | 43篇 |
污染及防治 | 60篇 |
评价与监测 | 7篇 |
社会与环境 | 13篇 |
出版年
2023年 | 10篇 |
2022年 | 14篇 |
2021年 | 13篇 |
2020年 | 10篇 |
2019年 | 4篇 |
2018年 | 9篇 |
2017年 | 19篇 |
2016年 | 13篇 |
2015年 | 4篇 |
2014年 | 5篇 |
2013年 | 16篇 |
2012年 | 10篇 |
2011年 | 19篇 |
2010年 | 9篇 |
2009年 | 15篇 |
2008年 | 13篇 |
2007年 | 8篇 |
2006年 | 6篇 |
2005年 | 5篇 |
2004年 | 8篇 |
2003年 | 13篇 |
2002年 | 5篇 |
2001年 | 5篇 |
2000年 | 2篇 |
1999年 | 5篇 |
1998年 | 1篇 |
1997年 | 4篇 |
1996年 | 1篇 |
1994年 | 3篇 |
1990年 | 1篇 |
1968年 | 1篇 |
排序方式: 共有251条查询结果,搜索用时 15 毫秒
81.
Palut JM Montarnal P Gautschi A Tevissen E Mouche E 《Journal of contaminant hydrology》2003,61(1-4):203-218
A long-term single borehole diffusion experiment using tritiated water as tracer was carried out in Opalinus clay, an argillaceous rock formation that is accessible at the Mont Terri Underground Research Laboratory, situated in the Swiss Jura. The tracer was diluted in reconstituted formation water and introduced into a packed-off section of a borehole located in saturated rock. Pressure in this interval was maintained equal to the pore pressure of the surrounding rock in order to prevent any hydraulic gradient around the borehole and to avoid advective transport processes. The evolution of the tracer concentration in the injection system was monitored over time. After 1 year of diffusion, the claystone surrounding the interval was retrieved by overcoring the whole borehole and packer system, and by an adjacent oblique borehole. Compressed air was used as drilling fluid to reduce rock disturbances. The recovered overcore was sampled along profiles perpendicular to the borehole wall with a view to determining the tracer-concentration profiles in the rock. To avoid further evaporation of tritiated water, subsamples were immediately transferred into polyethylene bottles and disaggregated by adding a known amount of tracer-free water. Fifteen profiles were determined and showed a decreasing tracer concentration with distance into the rock. The pore-water contents were constant along those profiles, confirming that only very little water was lost during overcoring operations. The evolution of tritium-tracer concentration in the injection system over time and in situ profiles were interpreted with a 3-D numerical simulation of the experiment. That allowed for the identification of the transport parameters (orthotropic diffusion tensor and porosity) by minimising the relative quadratic error between the experimental and simulated data. The fitting is good and the results are consistent with data obtained on drill-core samples. The result of tritiated water is discussed regarding (1) the potential effect of mechanical and/or chemical disturbances around the injection borehole and (2) the specific behaviour of tritiated water. 相似文献
82.
Numerical simulation tools have been used to study the dominating processes during transport of aromatic hydrocarbons in the unsaturated soil zone. Simulations were based on field observations at an experimental site located on a glacial delta plain with pronounced layered sedimentary structures. A numerical model for transport in the unsaturated zone, SWMS-3D, has been extended to incorporate coupled multispecies transport, microbial degradation following Monod kinetics and gas diffusive transport of oxygen and hydrocarbons. The flow field parameters were derived from previous work using nonreactive tracers. Breakthrough curves (BTC) from the hydrocarbon field experiment were used to determine sorption parameters and Monod kinetic parameters using a fitting procedure. The numerical simulations revealed that the assumption of homogeneous layers resulted in deviations from the field observations. The deviations were more pronounced with incorporation of reactive transport, compared with earlier work on nonreactive transport. To be able to model reasonable BTC, sorption had to be reduced compared to laboratory experiments. The initial biomass and the maximum utilisation rate could be adjusted to capture both the initial lag phase and the overall degradation rate. Nevertheless, local oxygen limitation is predicted by the model, which was not observed in the field experiment. Incorporation of evaporation and diffusive gas transport of the hydrocarbons did not significantly change the local oxygen demand. The main cause of the observed discrepancies between model and field are attributed to channelling as a result of small-scale heterogeneities such as biopores. 相似文献
83.
俄罗斯年产天然气5000×108m3,年输天然气2400×108m3,输气干线多采用多管线并列埋设方式。大量的长输管道、加压站和地下储气库的设计和施工都必须解决相应的环境保护问题。在河床处多采用埋管的办法;在沙漠地带要尽可能避开流沙地区;在永冻地区应注意输气管道的加热效应;过铁路的交叉口应设计自动监测系统;在确定管道线路时,必须注意生态保护;用植树绿化等方法尽量减轻加压站内燃气轮机发出的噪音危害;地下储气库的环境保护重点是回注水的处理。最后阐述了管道等输气工程的工作程序及所使用的法规和标准等。 相似文献
84.
The inhibitory effect of CH3F on methanogenesis in mesophilic anaerobic granules was tested at different concentrations (0-10% v/v, in the gas phase) and verified by the stable carbon isotopic signatures of CH4 and CO2. The results showed that the inhibitory effect increased with the initial CH3F concentration up to 5%. The CH3F concentration causing 50% metabolic inhibition was 0.32%. Complete inhibition of acetoclastic methanogenesis with a 91% reduction in total methanogenic activity was achieved when 5% CH3F was initially added to the headspace, which resulted in 870 μM dissolved CH3F in the liquid. It was much higher than that applied in other natural anoxic non-granular systems, indicating that the layered granular structure influenced the inhibitory effect. The obvious increase in hydrogen content indicated that high concentrations of CH3F (?5%) suppressed hydrogenotrophic methanogenesis as well. The stable inhibition lasted for at least 6 d as the CH3F concentration decreased slowly with incubation time. These results suggested that CH3F could be used for investigating methanogenic processes in anaerobic granular systems after the CH3F concentration and incubation time for specific inhibition of acetoclastic methanogenesis were carefully determined. In the present system, CH3F concentration of 5% was suggested to be optimal. 相似文献
85.
MacLeod M von Waldow H Tay P Armitage JM Wöhrnschimmel H Riley WJ McKone TE Hungerbuhler K 《Environmental pollution (Barking, Essex : 1987)》2011,159(5):1442-1445
We present two new software implementations of the BETR Global multimedia contaminant fate model. The model uses steady-state or non-steady-state mass-balance calculations to describe the fate and transport of persistent organic pollutants using a desktop computer. The global environment is described using a database of long-term average monthly conditions on a 15° × 15° grid. We demonstrate BETR Global by modeling the global sources, transport, and removal of decamethylcyclopentasiloxane (D5). 相似文献
86.
为了解常州市冬季大气污染特征,对2013—2015年常州市冬季PM2.5、PM10、SO2、NO2、CO数据进行分析,并结合HYSPLIT 4.9模式研究不同气团来源对常州市各污染物浓度的影响及潜在污染源区分布特征.结果表明,常州市冬季以PM2.5污染为主,其占冬季首要污染物的90%以上,冬季PM2.5小时浓度对应的空气质量级别以良和轻度污染出现频次最多,冬季的ρ(PM2.5)对ρ(PM2.5)年均值的贡献率高达37.4%,不完全燃烧是颗粒物的一个重要来源.冬季ρ(PM2.5)、ρ(PM10)、ρ(SO2)、ρ(NO2)和ρ(CO)的日变化均呈双峰分布,两个峰值分别出现在交通的早高峰和晚高峰附近.ρ(NO2)在晚高峰明显大于早高峰,而ρ(SO2)和ρ(CO)表现为早高峰大于晚高峰.常州市CO/NOx和SO2/NOx的分析结果表明,常州市交通源的贡献明显,点源对常州市的空气质量的影响也较大.1和6 h的ρ(PM2.5)梯度变化可判识细颗粒物的爆发性增长.冬季常州市受到西北、西和西南等地区的大陆性气流影响较大,其对应的ρ(PM2.5)、ρ(PM10)、ρ(SO2)、ρ(NO2)和ρ(CO)平均值相对较高,且对应的污染轨迹出现概率较大.偏东方向的气流由于移动速度慢,不利于污染物扩散易造成污染累积,导致ρ(PM2.5)、ρ(SO2)和ρ(NO2)相对较高.WPSCF(源区分布概率)高值区(>0.5)集中于从芜湖至上海的长江中下游区域和杭州湾区域.PM2.5、PM10、SO2、NO2和CO潜在源区存在较大差异性,NO2、SO2和CO本地化的潜在贡献较PM2.5和PM10更明显.此外,受船舶等影响海洋源区对NO2、SO2和CO的潜在贡献较大.研究显示,长三角区域的大气污染物以本地污染为主,但远距离污染输送贡献也不容忽视. 相似文献
87.
Mahsa Kheirandish Chunjiang An Zhi Chen Xiaolong Geng Michel Boufadel 《Frontiers of Environmental Science & Engineering》2022,16(5):61
88.
Andrea Cucco Georg Umgiesser Cristian Ferrarin Angelo Perilli Donata Melaku Canu Cosimo Solidoro 《Ecological modelling》2009
In this work the flushing features of a tidal active coastal basin, the Venice lagoon, have been investigated. The water transport time scale (TTS) has been computed by means of both an eulerian and a lagrangian approach. The obtained results have been compared in order to identify the main differences between the two methods. 相似文献
89.
一株高效1,4-雄烯二酮降解菌的筛选、鉴定及其降解转化特性研究 总被引:1,自引:0,他引:1
从养殖场废水中筛选出1株1,4-雄烯二酮(ADD)高效降解菌株ADD3,经过16S rDNA序列同源性分析,鉴定该菌株为芽孢杆菌(Bacillus sp.).通过单因素实验研究了不同实验条件对菌株ADD3降解特性的影响,采用高效液相色谱与质谱联用技术(UPLC-MS/MS)和高效液相色谱与四级杆飞行时间高分辨率质谱联用技术(UPLC-QTof-MS)鉴定转化产物.结果表明:菌株ADD3通过共代谢方式转化ADD,在MH肉汤培养基中降解500 μg·L-1 ADD的半衰期为3.6 h;葡萄糖、乙酸钠、蔗糖和淀粉对菌株ADD3降解ADD均有一定的促进作用,其中,最佳碳源为淀粉,最佳浓度为1000 mg·L-1;最佳pH和温度分别为7和40℃.实验中共鉴定出5种产物,降解机理主要包括加氢还原、脱氢氧化和羟基化,TP1(雄烯二酮)为主要产物.研究结果可为探索微生物转化ADD的机理、优化去除ADD的研究提供参考,并为构造相关工程菌提供一些基础数据. 相似文献
90.
Chengjie Xue Juan Wu Kuang Wang Yunqiang Yi Zhanqiang Fang Wen Cheng Jianzhang Fang 《Frontiers of Environmental Science & Engineering》2021,15(5):101